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1) Liu, J. Tian, Y. Shi, J. Zhang, S. Cai, Q.* An Enantioselective Synthesis of Spirobilactams through Copper-Catalyzed Intramolecular Double N-arylation and Phase Separation. Angew. Chem. Int. Ed. 2015, 54, 10917.2) Yang, W. Liu, Y. Zhang, S. Cai,Q.* Copper-Catalyzed Intramolecular Desymmetric Aryl C-O Coupling for the Enantioselective Construction of Chiral Dihydrobenzofurans and Dihydrobenzopyrans. Angew. Chem. Int. Ed. 2015, 54, 8805.3) Shi, J. Wang, T. Huang, Y. Zhang, X.* Wu, Y.-D.* Cai, Q.* Pd-Catalyzed Asymmetric Intramolecular Aryl C-O Bond Formation with SDP(O) Ligand: Enantioselective Synthesis of (2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methanols. Org. Lett. 2015, 17, 840 (ACS Editors¡¯ Choice Article).4) Zhou, F. Cheng, G.-J. Yang, W. Long, Y. Zhang, S. Wu, Y.-D. Zhang, X.* Cai, Q.* Enantioselective Formation of Cyano-Bearing All-Carbon Quaternary Stereocenters: Desymmetrization by Copper-Catalyzed N-Arylation. Angew. Chem., Int. Ed. 2014, 53, 9555.5) Zhou, F. Guo, J. Liu, J. Ding, K. Yu, S.* Cai, Q.* Copper-Catalyzed Desymmetric Intramolecular Ullmann C?N Coupling: An Enantioselective Preparation of Indolines. J. Am. Chem. Soc. 2012, 134, 14326.

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